期刊
MOLECULAR PHYSICS
卷 109, 期 4, 页码 625-638出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/00268976.2010.544263
关键词
ionic liquids; electric fields; electromagnetic fields; conductivity; diffusion
The non-thermal effects of external electric and electromagnetic fields in the microwave to far-infrared frequency range and at (r.m.s.) electric field intensities of 10-3 to 0.25 V/angstrom r.m.s. on neat salts of 1,3-dimethyl-imidazolium hexafluorophosphate ([dmim][PF6]) and 1-butyl-3-methyl-imidazolium hexafluorophosphate ([bmim][PF6]) have been investigated by means of non-equilibrium molecular dynamics simulation. Significant alterations in molecular mobility were found vis-a-vis zero-field conditions. Using Green-Kubo and transient time correlation function analysis, the electrical conductivity of these ionic liquids has been estimated. The results indicate that ionic liquids respond most significantly to frequencies much lower than those of smaller polar solvents such as water, although the mechanism of the field response is almost exclusively translational.
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