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INVITED TOPICAL REVIEW The structure of ambient water

期刊

MOLECULAR PHYSICS
卷 108, 期 11, 页码 1415-1433

出版社

TAYLOR & FRANCIS LTD
DOI: 10.1080/00268971003762134

关键词

x-ray and neutron scattering; x-ray absorption and emission spectroscopy; mixture and continuum models; empirical and ab initio theory

资金

  1. NSF
  2. Department of Energy

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We review the spectroscopic techniques and scattering experiments used to probe the structure of water, and their interpretation using empirical and ab initio models, over the last 5 years. We show that all available scientific evidence overwhelmingly favors the view of classifying water near ambient conditions as a uniform, continuous tetrahedral liquid. While there are controversial issues in our understanding of water in the supercooled state, in confinement, at interfaces, or in solution, there is no real controversy in what is understood as regards bulk liquid water under ambient conditions.

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