期刊
SCIENCE OF THE TOTAL ENVIRONMENT
卷 530, 期 -, 页码 110-119出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.scitotenv.2015.05.005
关键词
Carbonaceous aerosols; Secondary organic carbon; PAHs; n-Alkanes; PMF; Sanya
资金
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB05060500, XDA05100401]
- Ministry of Science and Technology of the People's Republic of China [2013FY112700]
- National Natural Science Foundation of China [41230641]
PM2.5 samples were collected in Sanya, China in summer and winter in 2012/2013. Organic carbon (OC), elemental carbon (EC), and non-polar organic compounds including n-alkanes (n-C-14-n-C-40) and polycyclic aromatic hydrocarbons (PAHs) were quantified. The concentrations of these carbonaceous matters were generally higher in winter than summer. The estimated secondary organic carbon (OCsec) accounted for 38% and 54% of the total organic carbon (TOC) in winter and summer, respectively. The higher value of OCsec in addition to the presences of photochemically-produced PAHs in summer supports that photochemical conversions of organics are much active at the higher air temperatures and with stronger intense solar radiation. Carbon preference index (CPI) and percent contribution of wax n-alkanes suggest that anthropogenic sources were more dominant than derivation from terrestrial plants in Sanya. Diagnostic ratios of atmospheric PAHs further indicate that there was a wide mix of pollution sources in winter while fossil fuel combustion was the most dominant in summer. Positive Matrix Factorization (PMF) analysis with 18 PAHs in the winter samples found that motor vehicle emissions and biomass burning were the two main pollution sources, contributing 37.5% and 24.6% of the total quantified PAHs, respectively. (C) 2015 Elsevier B.V. All rights reserved.
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