期刊
SCIENCE CHINA-CHEMISTRY
卷 59, 期 2, 页码 195-198出版社
SCIENCE PRESS
DOI: 10.1007/s11426-015-5528-1
关键词
enamide; photochemistry; visible light; trifluoromethylation; radical
资金
- National Natural Science Foundation of China [21472084, 81421091]
- Qing Lan Project of Jiangsu Province
- State Key Laboratory of Bioorganic & Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences
An efficient and practical method is developed for the trifluoromethylation of enamides using Umemoto's reagent as the trifluoromethylating reagent. These reactions proceeded under visible light irradiation without any photocatalyst at room temperature in good chemical yields.
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