4.7 Article

A highly efficient electrochemical route for the conversion of aldehydes to nitriles

期刊

SCIENCE CHINA-CHEMISTRY
卷 58, 期 4, 页码 747-750

出版社

SCIENCE PRESS
DOI: 10.1007/s11426-015-5331-z

关键词

electrosynthesis; nitriles; aldehyde; ammonia iodide

资金

  1. National Natural Science Foundation of China [21172079]
  2. Science and Technology Planning Project of Guangdong Province [2011B090400031]

向作者/读者索取更多资源

Using NH4I as the supporting electrolyte as well as the precursor of an I-2 promoter and nitrogen source, a highly efficient electrochemical route was developed to convert aldehydes to nitriles with excellent yields under mild reaction conditions. This electrochemical process could effectively avoid the direct use of NH3 gas, molecular iodine, and oxidants.

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