期刊
SCIENCE CHINA-CHEMISTRY
卷 58, 期 4, 页码 747-750出版社
SCIENCE PRESS
DOI: 10.1007/s11426-015-5331-z
关键词
electrosynthesis; nitriles; aldehyde; ammonia iodide
资金
- National Natural Science Foundation of China [21172079]
- Science and Technology Planning Project of Guangdong Province [2011B090400031]
Using NH4I as the supporting electrolyte as well as the precursor of an I-2 promoter and nitrogen source, a highly efficient electrochemical route was developed to convert aldehydes to nitriles with excellent yields under mild reaction conditions. This electrochemical process could effectively avoid the direct use of NH3 gas, molecular iodine, and oxidants.
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