期刊
MINI-REVIEWS IN ORGANIC CHEMISTRY
卷 6, 期 4, 页码 367-377出版社
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/157019309789371613
关键词
N-Arylindole; indole; cross-coupling; transition metal-catalyst; aromatic nucleophilic substitution reaction
资金
- program for New Century Excellent University Talents
- State Education Ministry of China [NCET-06-0868, 20070712025]
- Key Project of Chinese Ministry of Education [107105]
- Research Fund for the Doctoral Program of Higher Education of China
N-Arylindoles are known to be important subunits due to their key role in medically biological activities. This mini-review initially covers the important advances on the N-arylation of indoles with aryl halides by palladium, copper or other transition metals-catalyzed cross-coupling reactions in recent ten years. Subsequently, the synthesis of N-arylindoles from indoles with aryl halides, activated by electron-withdrawing substituents, by aromatic nucleophilic substitution reactions (SNAr) is also surveyed.
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