Effect of water quality on the leaching of a low-grade copper sulfide ore

Copper extractions from a low-grade, ground copper sulfide ore (0.7% Cu) leached in three media were freshwater 'seawater' double-strength seawater and pH 1.5 >= pH 2; 84% extraction was achieved in pH 1.5 seawater in 28 days at 23 degrees C. Cu-oxide and carbonate dissolved completely and chalcocite was altered to secondary covellite, some of which persisted in all media for the duration of the 28-day experiment. Chalcopyrite and bornite were both oxidised more readily in saline water. Iron, sodium, potassium and sulfur (sulphate) concentrations in leach solutions diminished and the amounts of insoluble iron(III) reaction products increased with increased salinity and increased solution pH. While, overall, silicate dissolution was small, the amounts of poorly crystalline phases (both iron(III) and silica-rich phases) increased with increased salinity and were greater in pH 1.5 media. In the context of heap leaching, the increased amounts of secondary precipitates formed if saline water was used could result in lower extraction efficiency and the increased total dissolved solids, density and viscosity could result in increased energy costs for solution management at operations. The software package Geochemist's Workbench was evaluated by modelling the synthetic seawater - pH 2 test. It was possible to predict the evolution of the solution composition, the main species and phase boundaries at the start and end of leaching, and the formation of three reaction products in accord with experimental data by applying the React sliding function. The tests were conducted using a pulverised ore sample to increase dissolution reaction kinetics, particularly for chalcopyrite. Future tests should be conducted using ore particle sizes appropriate to heap leaching. The copper distribution within particles indicated that the test ore may not be suited to heap leaching because the surface exposure of copper sulfide grains is limited. Therefore reactor designs better suited to smaller sized particles with/without pre-treatment should be considered. (C) 2014 Elsevier Ltd. All rights reserved.