期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 179, 期 -, 页码 136-143出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.micromeso.2013.05.024
关键词
Ordered mesoporous carbon CMK-3; Electric double-layer capacitance; Partial graphitization; Fe catalyst; Edge plane
类别
资金
- New Energy and Industrial Technology Development Organization (NEDO)
- Murata Science Foundation
- TEPCO Memorial Foundation
- Foundation for Promotion of Material Science and Technology of Japan
- Yokohama Academic Foundation
We have attempted to improve the electric double-layer capacitance of the ordered mesoporous carbon CMK-3 as a replica of mesoporous silica SBA-15, by partial graphitization during carbonization at 1000 degrees C with the aid of an Fe oxide catalyst. For a loading of 0.2 mmol Fe per 1 g of SiO2, CMK-3 consisting of partially graphitized carboneous rods with a 2d-hexagonally ordered structure was successfully obtained and showed a higher specific capacitance of 6.8 mu F cm(-2) in the electric double-layer capacitance measurement using Et4NBF4 as an electrolyte, compared to 4.1 mu F cm(-2) for conventional CMK-3. This was probably due to exposure of the edge planes of the graphitic domains on the surface of the carboneous rods, increasing the number of sites highly capable of adsorbing the electrolytes. (C) 2013 Elsevier Inc. All rights reserved.
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