期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 170, 期 -, 页码 189-193出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.micromeso.2012.11.032
关键词
Zeolite; Nanoparticles; Microwaves; XPS; Platinum
类别
资金
- Consejo de Desarrollo Cientifico y Humanistico of the Universidad Central de Venezuela (CDCH-UCV) [PI-0873252008]
The purpose of this study was the preparation of Pt and Pt-Sn catalysts supported on a HY zeolite (Si/Al = 3) induced by microwave radiation as heating source. The solids were characterized by means of X-ray diffraction (XRD), elemental chemical analysis, nitrogen physisorption at -196 degrees C, and X-ray photoelectron spectroscopy (XPS). Catalytic activity of the solids was evaluated using the toluene hydrogenation reaction. The XRD analysis showed that the zeolite structure was maintained after metal deposition. XPS revealed the presence of Pt-0 species in monometallic catalyst, while in bimetallic Pt-Sn catalysts, Pt-0 and SnOx species were found, which seem to be strongly interacting. The toluene hydrogenation reaction showed a drastic decrease in activity for bimetallic Pt-Sn catalyst, which was attributed to either a geometric and/or electronic interaction taking place on the Pt sites and tin species, avoiding, toluene adsorption. (C) 2012 Elsevier Inc. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据