期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 157, 期 -, 页码 89-93出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.micromeso.2012.01.015
关键词
Porous coordination polymer; Metal-organic framework; Water adsorption; Heat transformation
类别
资金
- Grants-in-Aid for Scientific Research [23750157] Funding Source: KAKEN
Four MIL-101-type porous coordination polymers were synthesized containing different substituents (-H, -NO2, -NH2, -SO3H) in the ligand and their water sorption properties were investigated. All of the compounds adsorbed huge amounts of water (ca. 0.8-1.2 g g(-1)) and the adsorbed water can be released at relatively low temperatures (ca. 353 K). In addition, the trapping pressure of water adsorption was found to be controlled by changing the substituents, varying the hydrophobicity of the functional groups. (C) 2012 Elsevier Inc. All rights reserved.
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