期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 142, 期 2-3, 页码 725-729出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.micromeso.2011.01.023
关键词
Hydrogen storage; Physisorption; Metal-organic frameworks; Thermal-desorption spectroscopy
类别
资金
- European Commission DG Research [SES6-2006-518271/NESSHY]
Hydrogen and deuterium adsorption sites in the crystalline MOF copper(II) benzene-1,3,5-tricarboxylate, Cu-BTC were studied by low-temperature thermal desorption spectroscopy. For a maximum loading of 218 D(2) molecules per unit cell of Cu-BTC three desorption maxima were observed. The maxima could be separated by either interrupted desorption or partial loading. By comparing to neutron diffraction studies from the literature the maxima could be assigned to three different adsorption sites, i.e. coordinatively-unsaturated Cu(2+) sites, tetrahedral side pockets and the large pores. (C) 2011 Elsevier Inc. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据