期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 127, 期 1-2, 页码 152-156出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.micromeso.2009.07.007
关键词
Mesoporous alumina; Aluminum tri-sec-butoxide; Cetyltrimethylammonium bromide; Stearic acid; Fluoride adsorption
类别
资金
- Korea Energy Management Corporation (KEMCO)
Two different kinds of mesoporous alumina samples were prepared using aluminum tri-sec-butoxide in the presence of either cetyltrimethylammonium bromide (MA-1) or stearic acid (MA-2) as a structure-directing agent, and tested for adsorptive removal of fluoride in water. Both materials contain a wormhole-like mesopore structure, but exhibited different textural properties: surface area (421 or 650 m(2)/g) and pore volume (0.96 or 0.59 cm(3)/g). These mesoporous aluminas demonstrated significantly improved adsorption capacity and faster kinetics to those of the commercial activated aluminas in fluoride removal by adsorption process. MA-2 prepared using stearic acid, in particular, demonstrated an adsorption capacity(14.26 mg/g)and initial adsorption rate(14.6 mg/g min) that were respectively 2.2 and 45 times higher than those of a commercial gamma alumina. The textural features of larger surface area and relatively smaller pore size in MA-2 compared to the activated aluminas are believed to be responsible for this enhancement in adsorption process. (C) 2009 Elsevier Inc. All rights reserved.
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