期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 118, 期 1-3, 页码 341-347出版社
ELSEVIER
DOI: 10.1016/j.micromeso.2008.09.005
关键词
Microwaves; Dealumination; Mordenite; Acidity; Porosity
类别
资金
- Ministerio de Educacion Ciencia
- FEDER funds [CrQ2005-02384/PPQ]
Commercial mordenite was partially dealuminated in HCl medium by conventional heating or under microwaves by refluxing or autoclaving at 373 K at different times. Samples were characterized by AAS, XRD, N-2 physisorption, FT-IR, Al-27 NMR, NH3-TPD, and SEM techniques. The acidity of the dealuminated samples was also determined by testing them as catalysts in two acid catalysed reactions: the isomerization of styrene oxide to obtain beta-phenylacetaldehyde, and the styrene oxide ring-opening reaction to give 2-ethoxy-2-phenylethanol. The use of microwaves, under autoclave or refluxing conditions, enhances dealumination, favours the later elimination of the Al extracted during washing, and affects the surface and acidic characteristics of the resulting samples. All catalysts showed similar low amounts of Bronsted acid sites. However, the catalyst treated under microwaves by autoclaving at shorter time (15 min) presented active acid centres with medium strength, and interestingly, lower amounts of strong Lewis acid sites (responsible for deactivation) than the rest of catalysts. These characteristics explain the total conversion obtained for this catalyst for the styrene oxide ring-opening reaction. (C) 2008 Elsevier Inc. All rights reserved.
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