期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 116, 期 1-3, 页码 246-252出版社
ELSEVIER
DOI: 10.1016/j.micromeso.2008.04.009
关键词
Mesoporous silica; Surface grafting; Adsorption; PPCPs; Water treatment
类别
资金
- National Science Foundation [CBET-0546370, CBET-0619349]
- NSF
- EPSCoR Puerto Rico Institute for Functional Materials
- UPRM Chemical Engineering
- National Center for Super Computer Applications [CTS060048]
- University of Illinois at Urbana-Champaign
MCM-41 type mesoporous silicates were functionalized with nickel species via thermal monolayer dispersion and grafting techniques, respectively. The material potential to serve as sorbents for the selective removal of a pharmaceutical drug (i = Naproxen) from water was tested via single component adsorption equilibria measurements at ambient conditions and C-i = 18 ppm. In general, the grafting technique provided the best strategy to avoid metal leaching. Although the anchoring of the nickel species was successfully accomplished, analysis of the textural properties of the resulting sorbent indicated that a considerable reduction in average pore size (ca. 1 nm), and hence surface area, limited the ultimate uptake capacity. Nevertheless, after normalization with respect to accessible surface area, the grafted sorbents offered capacities comparable to those exhibited by a traditional activated carbon (0.42 vs. 0.67 mu mol/m(2)). Ab initio and density functional theory calculations were employed to estimate the surface interaction energies for single sorbent clusters and attempt to describe the adsorption mechanism. Full optimization of the structures showed that the sorbate-sorbent interactions were at the weak-chemisorption level (similar to 15 kcal/mol), which is suitable for ultrapurification applications and sorbent regeneration via simple engineering means. In addition, a natural bond orbital analysis indicated that the interaction between the Naproxen and the nickel functionality results in a redistribution of electrons within the most prominent orbitals in the transition metal center (i.e.. 4s and 3d). This suggests that the interaction between sorbate and sorbent could generate a metal complex, but further studies are required to validate this hypothesis and to determine a sorbent regeneration strategy. (C) Published by Elsevier Inc.
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