期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 116, 期 1-3, 页码 400-405出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.micromeso.2008.04.029
关键词
Pd nanoparticles; Mesoporous silica; Catalytic activity
类别
资金
- Teaching and Research Award Program for Outstanding Young Professors in Higher Education Institute (TRAPOYP)
- MOE
- Gansu Province, China
Pd nanoparticles of 6-10 nm in size have been synthesized by formalin reduction method and incorporated into mesoporous SBA-15 silica during hydrothermal synthesis. Characterizations of the Pd nanoparticles encapsulated in mesoporous silica (Pd/SBA-15) reveal that the Pd nanoparticles in the range of 6-10 nm are encapsulated within the surfactant micelles during mesoporous silica formation and well dispersed within the mesoporous SBA-15 channels. The pore size increases and the surface area decreases with the incorporation of the Pd nanoparticles into SBA-15. The catalytic activity of Pd/SBA-15 was investigated in Heck coupling reactions with activated and non-activated aryl substrates. The Pd/SBA-15 composite exhibits an excellent catalytic activity, low Pd leaching, and reuse ability of at least five recycles in air for the Heck carbon-carbon coupling reaction. (C) 2008 Elsevier Inc. All rights reserved.
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