期刊
MICROCHIMICA ACTA
卷 180, 期 5-6, 页码 437-443出版社
SPRINGER WIEN
DOI: 10.1007/s00604-013-0939-1
关键词
Electrochemical sensor; Ascorbic acid; Polyaniline; Silicotungstic acid; Carbon nanotubes
资金
- National Natural Science Foundation of China [21205031, 21075030]
- Foundation from Department of Education of Hubei Province [D20102501]
We report on an electrochemical sensor for the sensitive amperometric determination of ascorbic acid (AA). Aniline containing suspended silicotungstic acid and carbon nanotubes was electropolymerized on the surface of a glassy carbon electrode in a single step which provides a simple and controllable method and greatly improves the electrocatalytic oxidation of AA. The effects of scan rate, solution pH and working potential were studied. A linear relationship exists between the current measured and the concentration of AA in the range from 1 mu M to 10 mu M and 0.01 mM to 9 mM, with a limit of detection as low as 0.51 mu M (S/N = 3). The sensor is selective, stable and satisfyingly reliable in real sample experiments. In our eyes, it has a large potential for practical applications.
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