期刊
MICROCHIMICA ACTA
卷 170, 期 1-2, 页码 27-32出版社
SPRINGER WIEN
DOI: 10.1007/s00604-010-0380-7
关键词
Ionic liquid; DNA; Rutin; Carbon paste electrode
资金
- National Natural Science Foundation of China [20875023]
A DNA-modified carbon paste electrode (DNA-CPIE) was designed by using a mixture of the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate and paraffin oil as the binder. The electrochemistry of rutin at the DNA-CPIE was investigated by cyclic voltammetry and differential pulse voltammetry. Rutin exhibits a pair of reversible redox peaks in buffer solutions of pH 3.0, and respective electrochemical parameters are established. Under the optimal conditions, the oxidative peak current is linear with the concentration of rutin in the range from 8 x 10(-9) to 1 x 10(-5) mol L(-1), and the detection limit is 1.3 x 10(-9) mol L(-1) (at S/N = 3). The electrode exhibits higher sensitivity compared to DNA modified carbon paste electrode without ionic liquid and better selectivity comparing with electrodes without DNA. It also showed good performance, stability, and therefore represents a viable method for the determination of rutin.
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