期刊
MICROCHIMICA ACTA
卷 170, 期 1-2, 页码 59-65出版社
SPRINGER WIEN
DOI: 10.1007/s00604-010-0385-2
关键词
Ultrasound-assisted emulsification microextraction; Triazine herbicides; High performance liquid chromatography; Soil samples
资金
- Natural Science Foundations of Hebei [B2008000210, B2010000657]
- Scientific Research Foundation of Education Department of Hebei Province [2009132]
Ultrasound-assisted emulsification microextraction was applied to extract the herbicides simazine, atrazine, prometon, ametryn and prometryn from soil samples. They then were determined by HPLC with diode-array detection. Parameters that affect the extraction efficiency, such as the kind and volume of the extraction solvent, emulsification time and addition of salt, were optimized. Under the optimum conditions, the following analytical figures of merits are found: enrichment factors between 145 and 222, limits of detection between 0.1 to 0.5 ng g(-1), analytical linearity in the range from 1.0 to 200 ng g(-1), correlation coefficients (r) between 0.9989 and 0.9998, relative standard deviations from 2.8% to 3.6% (at n = 5, intraday) and 3.7% to 4.3% (interday), and recoveries (at spiking levels of 5.0 and 50.0 ng g(-1)) from 82.6% to 92.0%. The technique is simple, practical, rapid, and environmentally friendly.
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