期刊
MICROCHEMICAL JOURNAL
卷 94, 期 1, 页码 1-6出版社
ELSEVIER
DOI: 10.1016/j.microc.2009.08.003
关键词
Solid phase microextraction; Sol-gel technology; Organophosphorus pesticides; Gas chromatography-mass spectrometry
A method based on immersed solid-phase microextraction (SPME) and gas chromatography mass spectrometry detection (GC-MS) for the determination of organophosphorous pesticides (OPPs) in aqueous samples was developed. A sol-gel based coating fiber was prepared using 3-(trimethoxysilylpropyl) amine as precursor. The synthesized fiber was prepared in a way to impart polar moiety into the coating network and would be more suitable for extracting polar and semi-polar organic pollutants. Important parameters influencing the extraction process were optimized and an extraction time of 40 min at 30 degrees C gave maximum peak area, when NaCl (20% w/v) was added to the aqueous sample. The linearity for disulfoton, phorate and sulfotep was in the concentration range of 0.01 to 5 ng mL(-1) and for parathion and O,O,O-triethylthiphosphate was in the range of 0.01 to 50 ng mL(-1). Limits of detection ranged from 1 ng L-1, for parathion, to 0.05 ng L-1, for disulfoton using time-scheduled selected ion monitoring (SIM) mode, and the RSD% values were all below 10.5% at the 1 ng mL(-1) level. The developed method was successfully applied to real water samples while the relative recovery percentages obtained for the spiked water samples were from 80 to 115%. (C) 2009 Elsevier B.V. All rights reserved.
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