4.6 Article

Local Atomic Structure of a High-Entropy Alloy: An X-Ray and Neutron Scattering Study

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DOI: 10.1007/s11661-012-1474-0

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  1. U.S. Department of Energy (DOE), Office of Science [DE-AC02-06CH11357]
  2. US Department of Energy, Office of Science, Office of Basic Energy Science [DE-AC52-06NA25396]
  3. Department of Energy EPSCoR [DE-FG02-08ER46528]
  4. U.S. Department of Energy (DOE) [DE-FG02-08ER46528] Funding Source: U.S. Department of Energy (DOE)

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By using high-energy synchrotron X-ray and neutron scattering, the local structure of a ternary high-entropy alloy Zr1/3Nb1/3Hf1/3 is characterized by means of pair distribution function (PDF) analysis. Results show that this alloy is a body center cubic (b.c.c.) phase in both bulk sample and in a thin film similar to 1.5 A mu m thick. The PDFs obtained from X-ray diffraction and neutron diffraction agree well with each other. The measured PDFs differ from the calculated PDF, particularly in the peak shape of the first two peaks, indicating local lattice distortion due to different atomic sizes in the solid solution. DOI: 10.1007/s11661-012-1474-0 (C) The Minerals, Metals & Materials Society and ASM International 2012

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