期刊
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE
卷 42A, 期 8, 页码 2259-2263出版社
SPRINGER
DOI: 10.1007/s11661-011-0652-9
关键词
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资金
- Michigan Public Service Commission
- U.P. Steel
- United States Department of Energy (DOE)
The temperature dependence of the microwave absorption of conventionally heated nonstoichiometric ferrous oxide (Fe(0.925)O) was characterized via the cavity perturbation technique between 294 K and 1373 K (21 A degrees C and 1100 A degrees C). The complex relative permittivity and permeability of the heated Fe(0.925)O sample slightly change with temperature from 294 K to 473 K (21 A degrees C to 200 A degrees C). The dramatic variations of permittivity and permeability of the sample from 473 K to 823 K (200 A degrees C to 550 A degrees C) are partially attributed to the formation of magnetite (Fe(3)O(4)) and metal iron (Fe) from the thermal decomposition of Fe(0.925)O, as confirmed by the high-temperature X-ray diffraction (HT-XRD). At higher temperatures up to 1373 K (1100 A degrees C), it is found that Fe(0.925)O regenerates and remains as a stable phase with high permittivity. Since the permittivity dominates the microwave absorption of Fe(0.925)O above 823 K (550 A degrees C), resulting in shallow microwave penetration depth (similar to 0.11 and similar to 0.015 m at 915 and 2450 MHz, respectively), the regenerated nonstoichiometric ferrous oxide exhibits useful microwave absorption capability in the temperature range of 823 K to1373 K (550 A degrees C to 1100 A degrees C).
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