4.2 Article

CuCl-catalyzed isomerization of gem-chlorofluorocyclopropanes into chlorofluoroalkenes

期刊

MENDELEEV COMMUNICATIONS
卷 23, 期 1, 页码 19-21

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ELSEVIER SCIENCE BV
DOI: 10.1016/j.mencom.2013.01.006

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资金

  1. Russian Federation [NSh-604.2012.3]
  2. Federal Target Program 'Scientific and Scientific Pedagogic Personnel of the Innovative Russia' [8431]
  3. Russian Academy of Sciences [OKh-01, P-08]

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CuCl-catalyzed isomerization of gem-chlorofluorocyclopropanes into chlorofluoroalkenes occurs as a result of the ring opening accompanied by the migration of chlorine atom. In the case of vinyl- or cyclopropyl-containing substrates, chlorofluoroalkadienes are formed.

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