期刊
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
卷 85, 期 10, 页码 2378-2385出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1070363215100254
关键词
oxidation; suberic acid; organic perrhenate; composite ionic liquid
资金
- National Science Foundation of China [21101085]
- Program for Liaoning Excellent Talents at the Liaoning Shihua University [LJQ2012031]
A series of quaternary ammonium perrhenate/3-hexyl-1-methyl-imidazolium hydrogen sulfate ([Hmim]HSO4) composite ionic liquids has been prepared. For the first time, the composite ionic liquids are used both as catalyst and solvent in oxidation of cyclooctene to suberic acid in the presence of hydrogen peroxide as a green oxidant. It was found that organic perrhenate salts play the important role in improving the selectivity of cyclooctene oxidation to suberic acid. The yield of suberic acid under the mild conditions is from good to high.
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