期刊
MENDELEEV COMMUNICATIONS
卷 21, 期 3, 页码 115-121出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.mencom.2011.04.001
关键词
-
资金
- Russian Academy of Sciences
- Russian Federation [4945.2010.3]
- Division of Chemistry and Materials Science of the RAS [1]
Among anodic (electro-oxidative) aromatic substitution reactions there is a specific group of reactions involving direct nucleophilic replacement of hydrogen atom at the aromatic ring, or S-N(H)(An) reactions. These reactions occurring via an intermediate sigma(+) complex represent a versatile type (the hydrogen atom that is easily removed as a proton) of S-N(H) reactions, on the one hand, and are somewhat similar to aromatic electrophilic substitutions, on the other hand.
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