期刊
MENDELEEV COMMUNICATIONS
卷 18, 期 3, 页码 150-152出版社
ELSEVIER
DOI: 10.1016/j.mencom.2008.05.013
关键词
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The title complex has been studied by H-1 and P-31 NMR spectroscopy and found to undergo reversible dissociation of its neutral ligands and interconversion. of its neutral and anionic ligands; the kinetic parameters of these processes and the crystal structure of the complex were determined; a new ligand exchange mechanism with unusual high spin-low spin transition during the ligand dissociation was suggested.
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