期刊
RUSSIAN CHEMICAL BULLETIN
卷 64, 期 3, 页码 712-717出版社
SPRINGER
DOI: 10.1007/s11172-015-0924-4
关键词
ortho-carboranes; nido-carboranes; cobalt bis(dicarbollide); cobalt derivatives
资金
- Russian Foundation for Basic Research [13-03-00581, 14-03-00925]
A partial degradation of 9,12-disubstituted derivatives of ortho-carboranes 9,12-X-2-1,2-C2B10H10 (X = Br, Alk, Ar) led to the corresponding substituted nido-carboranes [5,6-X-2-7,8-C2B9H10](-), which on the reaction with cobalt(II) chloride gave new 9,9',12,12'-tetrasubstituted derivatives of cobalt bis(dicarbollide) [9,9',12,12'-X-4-3,3'-Co(1,2-C2B9H9)(2)](-).
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