期刊
APPLIED SURFACE SCIENCE
卷 346, 期 -, 页码 278-283出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2015.03.210
关键词
Photocatalysis; Water splitting; Metal organic frameworks; CdS
类别
资金
- National Natural Science Foundation of China [51002001, 21303002]
- Research Fund for the Doctoral Program of Higher Education of China [20123401120004]
- State 211 Project of Anhui University, China
- Open Fund by Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control [KHK1403]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
CdS nanoparticles acting as photosensitizer was grown in situ upon UiO-66 metal-organic framework octahedrons through a hydrothermal process. The resultant CdS/UiO-66 hybrid photocatalysts show remarkably active hydrogen evolution under visible light irradiation as compared to CdS and UiO-66 alone. The optimum hybrid with 16 wt% CdS loading shows a hydrogen production rate of 235 mu mol h(-1), corresponding to 1.2% quantum efficiency at 420 nm. The improved photocatalytic hydrogen production over hybrid CdS/UiO-66 is ascribed to the efficient interfacial charge transfer from CdS to UiO-66, which effectively suppresses the recombination of photogenerated electron-hole pairs and thereby enhancing the photocatalytic efficiency. (C) 2015 Elsevier B.V. All rights reserved.
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