The mechanism study of trace Cr(VI) removal from water using Fe0 nanorods modified with chitosan in porous anodic alumina

Fe-0 nanorods modified with chitosan in porous anodic alumina (PAA) were prepared as adsorbent. Adsorption of trace Cr(VI) onto adsorbent was tested as a function of solution pH value, initial Cr(VI) concentration and adsorption time. The results showed that PAA can limit the size, disperse Fe-0 nanorods and protect them from oxidation. In the adsorption process, it was found that both PAA and chitosan can supply bridges between Fe-0 nanorods and Cr(VI) through the surface electrostatic attraction, and a small amount of PAA was etched. The optimum adsorption capacity obtained from the Langmuir model is 118.76 mg g(-1) which agrees with the experimental value at pH 5.0. X-ray photoelectron spectroscopy revealed that Cr(VI) was reduced to Cr(III) on the adsorbent surface. The adsorption behavior of Cr(VI) onto adsorbent was fitted well with the Langmuir model. The adsorption process followed the pseudosecond-order kinetic model, which implied that the adsorption process was chemisorptions. Intraparticle diffusion study shows that the internal diffusion of adsorbent is not the sole rate-controlling step. The Gibbs free energy change (Delta G degrees < 0) indicated that the process of Cr(VI) onto adsorbent was spontaneous. Besides, the aluminum sheets could be regenerated and be anodized to produce PAA. (C) 2014 Elsevier B.V. All rights reserved.