期刊
APPLIED SURFACE SCIENCE
卷 358, 期 -, 页码 223-230出版社
ELSEVIER
DOI: 10.1016/j.apsusc.2015.08.240
关键词
g-C3N4; TiO2 Hydrothermal-sonication; Visible light irradiation; Surface heterojunction
类别
资金
- National Basic Research Program of China [2013CB632402]
- NSFC [51472194]
Novel g-C3N4/Ti3+-TiO2 photocatalyst co-exposed {0 0 1} and {1 0 1} facets of TiO2 was synthesized via a hydrothermal-sonication assisted strategy. The photocatalytic activities of the as-obtained photocatalyst were evaluated by the degradation of rhodamine B (RhB) and the reduction of Cr(VI) under visiblelight irradiation. It was found that the g-C3N4/Ti3+-TiO2 composites with 6 wt% g-C3N4 exhibited the highest visible-light photocatalytic efficiency, which is also higher than the pure g-C3N4 and Ti3+-TiO2. A possible photocatalytic mechanism was discussed on the basis of the theoretical analyses and scavenger experiments. Results show that holes (h(+)) and superoxide anions (center dot O-2(-)) reactive species participated in the degradation of RhB solution over the g-C3N4/Ti3+-TiO2 composites. The enhanced photocatalytic activities of g-C3N4/Ti3+-TiO2 composites can be attributed to the wide optical adsorption of g-C3N4 and Ti3+ as well as the effectively separation and transportation of photo-generated electrons and holes pairs, which was resulted from the surface heterojunction between the g-C-3 N-4 and Ti3+-TiO2 nanosheets co-exposed {1 0 1} and {0 0 1} facets of anatase TiO2. (C) 2015 Elsevier B.V. All rights reserved.
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