Effect of Sm on hydrogen storage performance of La-Sm-Mg-Ni alloys

In this study, Sm was adopted in order to completely replace the expensive Pr/ Nd elements in the A2B7 type alloy. The results indicate that Sm is a favourable element for forming Ce2Ni7 type and Ce5Co19 type phases. With the increasing amount of Sm, the discharge capacity of the alloy retains a value of 283.3 mAh g(-1) at the current density of 1200 mA g(-1). The maximum discharge capacity of the alloys increases with the increasing Sm content when Mg content is relatively low. By optimising the composition and processing technology, the cycle life the alloy enhances from 74 cycles to more than 540 cycles, and the maximum discharge capacity also increases from 300 to 355 mAh g(-1).