Studies on the structure and gas sensing properties of nickel-cobalt ferrite thin films prepared by spin coating

The influence of Co2+ ions content on structure and sensing properties of Ni1-xCoxFe2O4 (x=0.25, 0.5, 0.75) thin films deposited on glass substrates by spin coating is presented. Structural characterization evidenced thin films with cubic spinel structures and morphologies dependent on cobalt content. Repartition of cations in spinel tetrahedral and octahedral sites was determined and was found that the presence of Co2+ ions in octahedral sites favor the formation of Fe2+ species. The sensitivity to some reducing vapor gases (acetone, liquefied petroleum gas LPG, ethyl alcohol and methyl alcohol) was investigated and was found that thin films with x = 0.75 exhibit high sensitivity to ethyl alcohol and thin films with x=0.25 have high sensitivity to acetone. This sensitivity largely depends on the temperature and test gas concentration and was related to the Fe2+ species formed in octahedral sites. (C) 2013 Elsevier B.V. All rights reserved.