High-rate performance of xLiFePO4•yLi3V2(PO4)3/C composite cathode materials synthesized via polyol process

xLiFePO(4)center dot yLi(3)V(2)(PO4)(3)/C composite cathode materials were synthesized via a polyol process, using LiOH center dot H2O, Fe-3(PO4)(2)center dot 8H(2)O, V2O5 and H3PO4 as raw materials, citric acid and PEG as carbon sources, and TEG as both a solvent and a reductant Structural and morphological characterizations of as-prepared materials were carried out by X-ray diffraction (XRD) as well as scanning electron microscopy (SEM), respectively. Furthermore, electrochemical properties of as-prepared materials were analyzed by charge-discharge tests, cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). XRD results indicated that the composites consisting of an olivine phase of LiFePO4 and a monoclinic phase of Li3V2(PO4)(3) are well-crystallized. It is found that the LF0.6P center dot LV0.4P/C composite exhibited better electrochemical performance than pristine LFP/C and LVP/C at 5 C and 10 C rate and delivered 126 mAh g(-1) and 110 mAh g(-1), respectively. The favorable particles morphology with less than 100 nm size and low extent agglomeration is believed as a factor. In addition, the co-existence of V3+-doped LiFePO4/C and Fe2+-doped Li3V2(PO4)(3)/C was supposed as another reason. (c) 2012 Elsevier B.V. All rights reserved.