Preparation and characterization of Au/CeO2-Al2O3 monoliths

Porous CeO2-Al2O3 monoliths with hierarchical pore structure were prepared by mixing boehmite particles with solutions containing different amounts of cerium chloride and aluminum nitrate. The monoliths were functionalized with gold nanoparticles using the incipient wetness method. The resulting materials were characterized by X-ray diffraction, nitrogen sorption, mercury porosimetry, UV-vis spectroscopy and transmission electron microscopy. The catalysts were tested in liquid phase glucose oxidation, comparing continuously stirred batch reactor and continuous-How fix-bed reactor setups. (C) 2012 Elsevier B.V. All rights reserved.