Synthesis and characterization of ZnO and TiO2 hollow spheres with enhanced photoreactivity

To study the relationship between the morphology and the photoreactivity of the catalyst, hollow spheres of two semiconductors of ZnO and TiO2 were synthesized by using sulfonated polystyrene (PS) as template. The catalyst samples were then characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), diffuse reflectance spectra (DRS), transmission electron microscopy (TEM) and N-2 sorption. Reactive brilliant red X3B, an anionic organic dye, was used in this study as a model chemical with the aim of organic pollutants control. The results show that, whatever the catalyst was, both the adsorptive ability and photoreactivity of the hollow spheres were much higher than that of nanoparticles. The adsorption and photoreactivity of ZnO hollow spheres increased by a factor of 7.36 and 4.66, respectively compared with ZnO nanoparticles, while 3.74 times increased in adsorption and 3.41 times increased in photoreactivity for TiO2 hollow spheres compared with TiO2 nanoparticles. Correlations between adsorption and photoreactivity reflected the importance of adsorption in the enhanced photoreactivity of ZnO and TiO2 hollow spheres. (C) 2009 Elsevier B.V. All rights reserved.