期刊
MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS
卷 33, 期 6, 页码 3374-3381出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.msec.2013.04.022
关键词
Ion-imprinted polymeric nanoparticles; K+ ion; Dicyclohexyl 18C6; Flame photometric determination; Precipitation polymerization
This work reports the first application of the ion imprinting technology for determination of potassium ion by precipitation polymerization method. Ion imprinted polymeric (IIP) nanoparticles were prepared by using dicyclohexyl 18C6 (DC18C6) as a K+ ion selective crown ether, in the acetonitrile-dimethylsulfoxide (3:1; v/v) mixture as porogen. The imprint potassium ion was removed from the polymeric matrix using 0.5 M HNO3. The scanning electron microscopy (SEM) micrographs showed colloidal nanoparticles of 60-90 nm in diameter and slightly irregular in shape. The obtained ion-imprinted particles for K+ showed selective recognition with rapid adsorption and desorption processes. It was found that imprinting results in increased affinity of the material toward K+ ion over other competitor metal ions with the same charge and/or close ionic radius. The synthesized IIP nanobeads were shown to be promising for solid-phase extraction coupled with flame photometry for determination of trace K+ ion in different water samples. (c) 2013 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据