期刊
MATERIALS RESEARCH-IBERO-AMERICAN JOURNAL OF MATERIALS
卷 17, 期 4, 页码 1071-1081出版社
UNIV FED SAO CARLOS, DEPT ENGENHARIA MATERIALS
DOI: 10.1590/1516-1439.284614
关键词
tinplate; temperature; bilayered systems; monolayered systems
资金
- CAPES (a Brazilian Governmental agency for the development of human resources)
- CNPq (the Brazilian National Council for Scientific and Technological Development)
Hybrid films obtained by a sol-gel process are based on two important reactions: hydrolysis and condensation. The condensation reaction is influenced by the curing temperature, since it induces the development of the intrinsic properties of the gel. The aim of this work is to coat tinplate, a substrate widely used in the packaging industry, with monolayered and bilayered hybrid films modified with polyethylene glycol and obtained through dip-coating. The results showed that the bilayered hybrid film obtained at 60 degrees C had a higher layer thickness, and the best performance in the electrochemical assays, as well as the most hydrophobic character, in relation to the other samples. For the monolayered systems, the 90 degrees C-cured system showed a lower layer thickness; however, this system showed a more compact, uniform and less porous layer, and presented better electrochemical impedance results, in comparison with the 60 degrees C-cured samples.
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