期刊
MATERIALS RESEARCH INNOVATIONS
卷 14, 期 5, 页码 370-374出版社
MANEY PUBLISHING
DOI: 10.1179/143307510X12820854748791
关键词
ZnO; TiO2; Dye sensitised solar cell; Electrolyte
资金
- National Natural Science Foundation of China [50842027, 90922028]
- National High Technology Research and Development Program of China [2009AA03Z217]
A ZnO modified TiO2 (ZnO/TiO2) film was prepared by immersing TiO2 electrodes in Zn(Ac)(2) aqueous solution. The open circuit voltage of a dye sensitised solar cell (DSSC) with the ZnO/TiO2 film electrode has a dramatic enhancement, compared to the DSSC with the TiO2 film electrode. However, the short circuit current density of the DSSC with the ZnO/TiO2 film electrode is lower than that with TiO2 electrode. The film electrodes were characterised by SEM, EDX and UV-vis, and the photoelectric performance of DSSCs were measured. The photovoltage enhancement is attributed to the formation of a flat-band potential energy barrier by ZnO at TiO2/electrolyte interface. The decline of the photocurrent with ZnO/TiO2 film electrode is due to poor dye absorption on larger particles of ZnO.
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