期刊
MATERIALS RESEARCH BULLETIN
卷 44, 期 4, 页码 785-788出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.materresbull.2008.09.018
关键词
Amorphous materials; Ceramics; Sol-gel chemistry; X-ray diffraction; Thermogravimetric analysis
Spherical alpha-alumina powders were prepared by the controlled hydrolysis of aluminum isopropoxide in a hydrolysis system consisting of octanol and acetonitrile. Diverse solvents to dissolve reactant formed diverse hydrolysis systems and affected particle shape of alpha-alumina powders. The precursors crystallized to gamma-alumina at 1000 degrees C and converted to alpha-alumina at 1150 degrees C without intermediate phases. The particle morphology of precursor was retained after it crystallized to alpha-alumina. The heating rate influenced the particle shape and the state of agglomeration during calcination process. The thermal properties of the precursors were characterized by thermal gravimetric and differential thermal analysis. X-ray diffraction technique was used to confirm the conversion of crystalline phase of alumina powders from amorphous to alpha-phase. Transmission electron microscopy was used to investigate the morphologies and size of the precursors and products. Crown Copyright (C) 2008 Published by Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据