期刊
MATERIALS RESEARCH BULLETIN
卷 44, 期 8, 页码 1700-1708出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.materresbull.2009.04.002
关键词
Oxides; Thin films; Crystal growth; Microstructure; Optical properties
A potentiostatic electrodeposition technique was used to directly fabricate large-scale, well-aligned, and single-crystal line submicron ZnO rod arrays on tin doped indium oxide glass substrate without a preprepared seed layer of ZnO from an aqueous solution only containing zinc nitrate. The effects of electrochemical parameters, such as electrodeposition potential, electrodeposition duration, solution temperature, and precursor concentration, on the orientation, morphology, aspect ratio, and growth rate of ZnO rod arrays were systematically investigated. Results show that submicron ZnO rod arrays with (0002) preferred orientation and perfect crystallization were obtained when electrodeposition potential was in the range from -0.6 to -1.1 V and solution temperature was controlled above 60 degrees C. Both high solution temperature and low precursor concentration resulted in the decrease in rod diameters. Photoluminescence measures showed that small diameter and nanotips of ZnO rod arrays should be responsible for strong and sharp ultraviolet emission in the room temperature photoluminescence spectra. (C) 2009 Published by Elsevier Ltd.
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