期刊
MATERIALS RESEARCH BULLETIN
卷 43, 期 12, 页码 3601-3606出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.materresbull.2008.01.004
关键词
Alloys; Chemical synthesis; X-ray diffraction; Impedance spectroscopy; Electrochemical properties
资金
- National Science Foundation of China [50372064, 20471057]
Composite Sn-SnSb nano-crystalline films were fabricated on Cu substrate by an electrochemical deposition process. X-ray diffraction, scanning electron microscopy, and galvanostatic cell cycling were used to characterize the structures and electrochemical properties of the films. The as-deposited films consist of only Sn/SnSb composite nanocrystals with it rather dense morphology. The Sn-SnSb composite electrode gives rise to a very small (6%) initial capacity loss and a rather high specific capacity of about 650 mAh/g, which is significantly higher than the values reported in the literature. The coulombic efficiency during charge-discharge cycles is close to 100%. (C) 2008 Elsevier Ltd. All rights reserved.
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