期刊
MATERIALS LETTERS
卷 106, 期 -, 页码 26-29出版社
ELSEVIER
DOI: 10.1016/j.matlet.2013.04.039
关键词
beta-RbSm(MoO4)(2); Synthesis; Crystal structure; Raman spectroscopy
资金
- SB RAS [28.12]
- RFBR [12-02-90806-mol_rf_nr]
- Ministry of Education and Science of the Russian Federation [16.518.11.7091]
Low-temperature rubidium samarium dimolybdate, beta-RbSm(MoO4)(2), microplates have been prepared by solid state synthesis at 723 K by 70 h and 893 K by 150 h. The crystal structure of beta-RbSm(MoO4)(2) has been first refined by the Rietveld method in the space group Pbcn with unit cell parameters a = 5.1431(2) angstrom, b=18.8195(7) angstrom, and c=8.1641(3) angstrom (R-B=4.82%). The crystal structure of beta-RbSm(MoO4)(2) consists of the layers of MoO4 tetrahedrons corner-sharing with SmO8 square antiprisms. About 20 narrow Raman lines have been observed in Raman spectra recorded for the beta-RbSm(MoO4)(2) powder sample. (C) 2013 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据