4.5 Article

Succinimidinium N-sulfonic acid hydrogen sulfate as an efficient ionic liquid catalyst for the synthesis of 5-arylmethylene-pyrimidine-2,4,6-trione and pyrano[2,3-d]pyrimidinone derivatives

期刊

RESEARCH ON CHEMICAL INTERMEDIATES
卷 42, 期 5, 页码 4443-4458

出版社

SPRINGER
DOI: 10.1007/s11164-015-2289-6

关键词

Aldehydes; Barbituric acid; 5-Arylmethylene-pyrimidine-2,4,6-trione; Pyrano[2,3-d]pyrimidinone; Succinimidinium N-sulfonic acid hydrogen sulfate ([SuSA-H]HSO4)

资金

  1. Iran National Science Foundation (INSF) [93014856]
  2. Research Council of the University of Guilan

向作者/读者索取更多资源

Succinimidinium N-sulfonic acid hydrogen sulfate ([SuSA-H]HSO4) as a new ionic liquid is prepared and characterized using a variety of techniques, including infrared spectra (FT-IR), H-1 and C-13 NMR, scanning electron microscopy, a mass spectra method, as well as by Hammett acidity function. The prepared reagent is efficiently able to catalyze the preparation of 5-arylmethylene-pyrimidine-2,4,6-triones via the condensation of aldehydes and barbituric acid. Further studies showed that the condensation of aldehydes with barbituric acid and malononitrile leading to pyrano[2,3-d]pyrimidinone derivatives can also be efficiently promoted in the presence of this reagent. The present methodology offers several advantages, including ease of the preparation and handling of the catalyst, simple and easy work-up, short reaction times, high yields of the products and recyclability of the catalyst.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.5
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据