Preparation and characterization of silica aerogels from oil shale ash

The silica aerogels were successfully synthesized using oil shale ash which is a by-product of oil shale processing via ambient pressure drying. The physical and textural properties of the silica aerogels have been investigated and discussed. The results showed that the organic modification of hydrogels was a crucial step during the processing which preserved mesopores in ambient pressure drying. The unmodified hydrogel underwent tremendous shrinkage during the drying and yielded microporous silica aerogel. Using this novel route, it could produce silica aerogel with low tapping density of 0.074 g/cm(3), high specific surface (909 m(2)/g) and cumulative pore volume of 2.54 cm(3)/g. From the industrial point of view, the present process is quite suitable for a large scale production of powdered silica aerogel. Furthermore, it provides a new way to solve the problem of oil shale ash pollution. (C) 2009 Elsevier B.V. All rights reserved.