期刊
MATERIALS CHEMISTRY AND PHYSICS
卷 148, 期 1-2, 页码 403-410出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2014.08.004
关键词
Inorganic compounds; Organic compounds; Amorphous materials; Sol-gel growth; Fourier transform infrared spectroscopy (FTIR); Nuclear magnetic resonance (NMR)
资金
- Ministerio de Ciencia e Innovacion [MAT2013-44463-R]
- Junta de Andalucia [FQM-346]
- Fondos Feder
- FWO-Vlaanderen (Fund Scientific Research - Flanders) [3E10813W]
The ethenylene bridges on the walls of an ethenylene-bridged periodic mesoporous organosilica were successfully modified with a variety of pyrrole derivatives - pyrrole, methylpyrrole, dimethylpyrrole, trimethylpyrrole and 1-phenylpyrrole - through Diels-Alder reactions. X-ray diffraction measurements and N-2 adsorption-desorption analysis confirmed the preservation of the ordering and mesoporosity of the parent material as well as the decoration of the pores with the surface Diels-Alder adducts. Moreover, other techniques such as DRIFT, C-13 and Si-29 nuclear magnetic resonances revealed the formation of the surface N-heterocyclic compounds at the parent ethenylene sites. (C) 2014 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据