期刊
MATERIALS CHEMISTRY AND PHYSICS
卷 137, 期 1, 页码 17-21出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2012.08.072
关键词
PANI; Silica; Dendritic; Nanofiber; Mesoporous; Interpenetrating polymer network
资金
- Natural Science Foundation (NSF) of China [21103122]
- Science Developing Foundation of Tianjin Education Committee [20060514]
- Natural Science Foundation from Tianjin University of Science and Technology [20070415]
A new method to prepare dendritic inorganic nanofibers by using dendritic polyaniline (PANI) nanofibers as templates was described. Dendritic PANI/silica composite nanofibers were synthesized via a self-assembly 501 gel progress. Both the organic and the inorganic phases were co-continuous and interpenetrated each other forming interpenetrating polymer network (IPN) structure. Mesoporous dendritic silica fibers were derived after removing the PANI component from the IPN structured PANI/silica fibers by calcinations. The diameters of the as-prepared silica fibers are tunable since the diameters of the PANI fibers could be controlled easily by changing the synthetic conditions. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), and N-2 adsorption/desorption isotherms experiments were employed to characterize the as-prepared nanomaterials. (C) 2012 Elsevier B.V. All rights reserved.
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