期刊
MATERIALS CHEMISTRY AND PHYSICS
卷 133, 期 2-3, 页码 1144-1151出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2012.02.028
关键词
Microporous materials; Crystallisation; Adsorption
资金
- CO2CRC
- CSC
Core-shell structures of zeolite X coated with silicalite as well as mesoporous (MCM-41) have been synthesized. Furthermore, the surfaces of the silicalite and mesoporous silica shells were silylated using organosilanes. The materials were characterized by X-ray diffraction, nitrogen adsorption/desorption, scanning and transmission electron microscopy. The results show that the properties of zeolite 13X@silicalite and zeolite 13X@mesoporous silica core-shells composite structures are well maintained even after the modification. As expected, the shell thickness increased with increase in synthesis time, however, the micropore volume decreased. Silylation with smaller organosilanes (trimethyl chlorosilane) resulted in decrease in surface area as they diffused through the pores; however, bulkier silane reacted with surface hydroxyl groups and maintained the pore structure. Contact angle measurements revealed that hydrophobicity of zeolite 13X was enhanced by the microporous and mesoporous shell coating and was further improved by silylation. (C) 2012 Elsevier B.V. All rights reserved.
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