期刊
MATERIALS CHEMISTRY AND PHYSICS
卷 134, 期 2-3, 页码 571-575出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2012.03.054
关键词
Garnet; Li; Ga; Cubic; Ionic conductivity; Hot-pressing
资金
- U.S. Army Research Laboratory (ARL)
- U.S. Army Research Office (ARO)
- United States Army Research Laboratory
Ga addition to the garnet Li7La3Zr2O12 (LLZO) can lead to stabilization of the cubic structure, high relative density and high Li-ion conductivity at room temperature. Cubic Li6.25La3Zr2Ga0.25O12 powders were prepared from co-precipitated nitrate precursor and consolidated by hot-pressing to a relative density of similar to 91%. The total Li-ion conductivity was similar to 3.5 x 10(-4) Scm(-1) while the electronic conductivity was similar to 7.1 x 10(-8) Scm(-1). The Ga substituted LLZO had a slightly higher total Li-ion conductivity compared to Al substituted LLZO of similar composition and relative density. This difference may be related to the larger size of Ga versus Al leading to different site occupancy fractions. Published by Elsevier Ltd.
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