期刊
MATERIALS CHEMISTRY AND PHYSICS
卷 118, 期 2-3, 页码 496-500出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2009.08.024
关键词
Oxides; Chemical synthesis; Electron microscopy; Microstructure
资金
- National High-Technology Research and Development Program of China [2006AA03A209]
- National Defense Fundamental Research [D1420061057]
- Education Ministry of China [NCET-05-0660]
- Fok Ying Tung Education Foundation [101049]
Hollow microspheres of hematite (alpha-Fe2O3) were prepared by a simple hydrothermal treatment of fibrous ammonium sulphate hexahydrate ((NH4)(2)Fe(SO4)(2)center dot 6H(2)O) aqueous solution without any surfactant and additives at 180-200 degrees C. The products were characterized by XRD, FE-SEM and TEM. The results show that alpha-Fe2O3 hollow microspheres are about 1 mu m in diameters and are composed of alpha-Fe2O3 nanoparticles with a diameter range from 50 mm to 150 nm. The effects of reaction parameters such as reaction time, temperature and [(NH4)(2)Fe(SO4)(2)center dot 6H(2)O] on the morphology of the final product were investigation A potential formation mechanism of alpha-Fe2O3 hollow microspheres was also proposed, where the in mediate, urchin-like goethite, served as a sacrificial template for the formation of hollow structure. reaction parameters-depended morphologies of the final products consisted well with the proper formation mechanism. (C) 2009 Elsevier B.V. All rights reserved.
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