期刊
MASS SPECTROMETRY REVIEWS
卷 27, 期 4, 页码 289-315出版社
WILEY
DOI: 10.1002/mas.20165
关键词
computer simulation; molecular dynamics; atomic SIMS; cluster SIMS; MALDI
类别
Surface based mass spectrometric approaches fill air important niche in the mass analysis portfolio of tools. The particular niche depends on both the underlying physics and chemistry of molecule ejection as well as experimental characteristics. In this article, we use molecular dynamics computer simulations to elucidate the fundamental processes giving rise to ejection of organic molecules in atomic and cluster secondary ion mass spectrometry (SIMS), massive cluster impact (MCI) mass spectrometry, and matrix-assisted laser desorption ionization (MALDI) mass spectrometry. This review is aimed at graduate students and experimental researchers.
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