期刊
MACROMOLECULES
卷 46, 期 10, 页码 3699-3707出版社
AMER CHEMICAL SOC
DOI: 10.1021/ma400181z
关键词
-
资金
- National Nature Science Foundation of China [21174085, 21274088]
- Science & Technology and Education Commission of Shanghai Municipal Government [12ZZ020]
- Shanghai Leading Academic Discipline Project [B202]
- [NCET-12-3050]
We herein demonstrated a novel multiresponsive fluorescent nanorod based on C-60, which is fabricated through the versatile coassembly of fullerene C-60 and anthracene-ended hyperbranched poly(ether amine) (AN-hPEA). The supramolecular nanorods (C-60@AN-hPEA) can be further cross-linked through photodimerization of anthracene, and the size of the obtained nanorods is 2-12 mu m in length and 50-90 nm in diameter. C-60@AN-hPEA nanorods are amphiphilic, responsive, and fluorescent. The fluorescence of C-60@AN-hPEA nanorods in aqueous solution is responsive to temperature and pH. The C-60@AN-hPEA-1/4 nanorods exhibit the interesting temperature-enhanced fluorescence, while the fluorescence intensity of AN-hPEA without C-60 decreases with the increasing temperature. Detailed fluorescence study revealed that the temperature-enhanced fluorescence behavior of C-60@AN-hPEA-1/4 nanorods might be ascribed to the static quenching of the excited anthracene by C-60.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据